@Colin,
@Byron... what if I’m not really interested in breeding them? Is it still better to get pairs?
I suspect that Colin like me thought breeding was the issue. So now for more general maintenance.
This is a shoaling species, so ideally (i.e., keeping the fish's "expectations" foremost) it needs a group of five minimum, in a 4-foot minimum length tank. Never less than five, there is a very real risk of a bully developing, or of a subordinate fish being picked on. I am going to post a video I have posted some time back, of a group of 11 wild
P. scalare fish in a fairly large tank [though in the comments the owner says he feels this tank is too restrictive and intends a larger, perhaps because he realizes pairs will form and that means more space] because this video shows better than words can describe how this beautiful fish should be kept to provide for its expectations. You will notice some interaction, a bit of head bunting and shoving, which is normal "harmless" behaviour that keeps the fish happy. Too few fish cause this normal interaction to seriously break apart, resulting often in dead fish.
A lone angelfish can manage, but I am not an aquarist who recommends keeping fish contrary to their inherent expectations. But I suppose it can work, though what the fish may think of it, I cannot say [nor can anyone else!]. A "pair" must be a bonded pair or they will likely not get along. Colin described the method of obtaining a bonded pair previously; let the fish select each other and that is usually successful...though individual fish can later change their mind. But it is less risky than throwing a male and female fish (which is not at all easy to tell to begin with esp in juvenile fish) together and hoping it works. This is just not fair to the fish, they cannot act differently from their natural instincts no matter what we may want.
Keep in mind though that a bonded pair will spawn. If they are on their own in the tank, this is no problem. If they have other fish, the other fish better stay well out of their space. A a male angelfish has a strong sense of his territory, which will be the entire tank in anything 4 feet in length and under.