Back when I did monthly water changes (last one was yesterday) I made sure to thoroughly vacuum as much debris from the gravel as possible so I'm a little confused how that could still be a major contributor. How exactly am I supposed to clean the filter? I was under the impression that the filter was a haven for helpful bacteria? Thanks
I listed the various factors that can cause nitrates, not suggesting all apply. But obviously one or more must, or you wouldn't have nitrates above 40 ppm. So your nitrates now may not be due to the substrate necessarily.
Bacteria in a freshwater aquarium are many and varied in function. Most aquarists think of the nitrifiers when they see "bacteria," and these are primarily in the filter but also in the substrate. The nitrifiers use ammonia to produce nitrite ( these are the
Nitrosomonas sp. bacteria) and then nitrite to produce nitrate (
Nitrospira sp.). There are then denitrifying bacteria that can use nitrate to change it back into nitrogen gas which enters the atmosphere.
Waste control bacteria are species of heterotrophic bacteria that break down dead organic matter like fish waste, dead fish or plant matter, uneaten fish food, dead bacteria, etc. Some are aerobic, but many species are facultative anaerobes, able to live with or without oxygen. Like all bacteria, they colonize surfaces, and these are most prevalent in the substrate and the filter media. Many species can survive complete drying, allowing them to remain potent even when filter media that has been previously used is completely dry. These bacteria have only one requirement to appear and live: organics. They compete with autotrophic bacteria for both oxygen and surface area; studies show that even in relatively clean environments, they occupy more than 50% of the available surface area. And given that they can reproduce within 15-60 minutes—compare this to the 12-32 hours required by nitrifying bacteria—you can see how easily these heterotrophic bacteria can overwhelm the system. In a filter, if sludge is allowed to increase, heterotrophic bacteria will multiply so fast they actually smother and kill the autotrophic nitrifying bacteria. Keeping the filter clean of organics (that brown sludge) is crucial to control this. Rinsing the filter media under the tap will not kill off all these bacteria as some think, though in new tanks using a bucket of tank water is OK.
Live plants usually mean lower nitrates, all else being equal, because the plants quickly take up ammonia and therefore less is used by bacteria so nitrite and thus nitrate are less. Plants also can take up some nitrate, especially the fast growers.
Seachem Prime was mentioned, and this conditioner detoxifies ammonia, nitrite and nitrate. However, this can be misleading, because the detoxification only lasts 24-48 hours, after which if it is still present, the ammonia or nitrite or nitrate reverts back to the toxic form. Prime should not be thought of as some sort of treatment for ammonia/nitrite/nitrate, but only as a temporary remover of whichever if they occur in the source water (which they don't here). Prime's detoxification of these allows the bacteria to take over after the initial influx of them with water changes. As I said, this is not what you have, but I just point it out. Nitrate occurring within the aquarium has to be dealt with by eliminating the source until you get the nitrate down to an acceptable level and it remains there from water change to water change. High levels of nitrate, above 40 ppm, have been shown to slow fish growth, suppress breeding, and depress the immune system making the fish much more susceptible to disease. While different fish species show some variation in tolerance, a level below 20 ppm is recommended, and preferably below 10 ppm.
Byron.