three-fingers
Fish Connoisseur
Basically, it seems to vary hugely from pond to pond and tank to tank. In most cases (for both aquariums and ponds) there's always a higher CO2 level than allowed by the air-water equilibrium in the morning, whether or not it drops to or below the air-water equilibrium levels during the day is what will vary hugely.i am not too sure about ponds, and whether there is a big difference to aquariums, there may well be higher CO2 levels than air, but once the plants start photosynthesisng this is quickly used and then the levels are lower than air.
That's not the case though. That would only be the case in tanks that get loads of water changes and/or gravel vacs and that have a lot of plant growth, like a high-tech planted tank without the CO2 injected.It is all to do with Equilibrium:
If you are adding CO2 artificially, you are raising the levels high above the natural equilibrium with the air. In this case, the more aeration you have, the more CO2 you lose from the water. So an airstone can be a problem if you are artificially adding CO2.
If you are not artificially adding CO2, then the levels are never going to be measurably above the equilibrium point with the air.
In the average aquarium (which I'm taking as having normal ~20% weekly water changes, low-medium number of plants, medium-high number of fish and low-medium lighting), the CO2 level will be higher than the air-water equilibrium level due to all respiring organisms such as fish and bacteria breaking down waste.
Walstad tanks are the extreme version, where CO2 levels can be very high, due to the decomposing soil substrate and extremely low frequency of water changes.
In a relatively squeaky-clean tank tank with high light and nothing else limiting the plants, this could be a great idea (if you didn't want the fast growth from CO2). But in a small man-made pond (of which most are basically like large Walstad tanks), it would lower the CO2 level towards the air-water equilibrium.But they can get below it, because the plants are using the CO2. So if you use an airstone in this situation, it will help the tank to stay in equilibrium with the air, and this will actually add CO2 to the water in this situation (although it will still be around the average of 8ppm - basically it keeps the levels steady)
I don't know where the "8ppm" level came from (an article or post somewhere?), but I'd be interested to find out. This level being mentioned supports what I'm saying - since water at equilibrium with air has 0.5ppm of CO2, much lower than 8ppm. The other 7.5ppm would be from respiring organisms.
But if this figure was from an experiment somebody on a forum had done using sterilised water and an airpump, I'd put it down to unreliable test kits.

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