I have one of those drain/fill kits (like Python) and never experienced any problems. Even out the temperature as best you can. Fill the bucket (if you use that mode) a little warmer then the tank temperature, put in your chemicals and bring it up to the tank. This way, you can wait a few minutes get a good feel for both temperatures. A slight difference in water temperature isn't going to do much. It is only 25% anyways.
With my fill kit, water comes straight out of the siphon and into the tank. As it is filling up I pour the dechlor around the tank. I haven't had any problems so far.
If you want to be totally crazy about this, you can heat it perfectly. Either way, it shouldn't really matter...
With my fill kit, water comes straight out of the siphon and into the tank. As it is filling up I pour the dechlor around the tank. I haven't had any problems so far.
If you want to be totally crazy about this, you can heat it perfectly. Either way, it shouldn't really matter...

I use a Python system and have never had a problem with adding my dechlorinator into the water stream as I'm filling the tank. 