When I first started doing water changes I was told not to use the hot tap because of dissolved copper in the water, so I started boiling water in the kettle. Then I was told not to do that because of possible limescale in the kettle! There was no way I was going to be standing around boiling pans of water (that was an accident waiting to happen) so now I just use the tap with no ill effects.
I'm another who has to sing the praises of Prime. I started off with a big bottle of the Tetra stuff, but several 90% water changes during my cycle saw a 250ml bottle of that off in no time. Then I bought a 500ml bottle of Prime and even with overdosing, I've hardly made a dent in it. Should last me a year at the very least! There's really no reason not to use Prime.