Well, it's fairly simple. As these are extraordinarily easy fish to breed, you just put some female mollies and male guppies in the tank. If you do this, then, theoretically (having never done this myself), you should have larger fish with guppy coloration. If I were you, I'd have at least two separate tanks available, one for all males, one for all females (otherwise the same species will breed with each other while they breed with the different species, making it difficult to separate the fry), then place the chosen females and half that number of males so as to not stress the females too much, and let them have at it. They will need a pH around 7.5. Keep the water warm and pristine and feed the fish a varied diet. You should see results. After breeding, put the males and females back into their tanks, raise the fry in a different tank, and send a new batch of males and females into the breeding tank.
You're going to need a lot of tanks.
Or you could just keep, I dunno, five of each in the main tank. They'll quickly populate it for you. My female molly just dropped forty fry in one go, so it's entirely plausible that only one or two spawns should fill your tank.