GH and pH are linked. If you have lots of minerals in the water, the pH will usually go up.
Tap Water Softeners can replace calcium with sodium and that is not good for fish. Calcium is actually good for guppies and other livebearers and you don't need to soften the water for them.
You need to find out what the GH (general hardness), KH (carbonate hardness) and pH of your water supply is before it goes through the water softener. This information can usually be obtained from your water supply company's website or by telephoning them. If they can't help you, take a glass full of tap water to the local pet shop and get them to test it for you. Write the results down (in numbers) when they do the tests. And ask them what the results are in (eg: ppm, dGH, or something else).
If your GH is above 200ppm, then it is fine for livebearers (guppies, platies, swordtails, mollies).
If the pH is above 7.0, it is fine for livebearers.