It depends on circulation of course but generally it works to wait at least 20 minutes after dosing before testing.
Yes, you've heard correctly. There are all sorts of things that make nitrate testing difficult (chemists have trouble with it too, not just amateurs) and one of them is that the test is not as reliable when there is high nitrite(NO2) present.
Since your nitrite(NO2) is now spiking, it's time to lower your dosing to as low as 2 or 3ppm, rather than 4-5ppm. This helps to slow down the negative effects on the bacteria of the hight processing rates that are happening. Much later, near the end of fishless cycling you will raise the dosing back up to 5ppm for the finish.
~~waterdrop~~