Yup, Prime is the one.  You want to dose for the full volume of the tank, not the volume of new water, when direct filling.  Using a dechlor product is partly about lowering the risk of a chlorine product overdose by the water authorities and dechlor products can be overdosed to give better protection against that small but possible chance.  If you are still in the process of maturing your bacterial colonies, ie. in the first year of a new tank, you don't want to overdose more than 2x.  Probably 1.5x to 2x would be a good recommendation.
I use a Python and since dosing Prime for my full tank volume at 1.5x to 2x is still only a partial capful, I find I like to guesstimate half of it and toss that into the filter output stream before the Python fill and then the other half toss right after the fill is finished.  I'm sure it doesn't really matter but it makes me feel good.
~~waterdrop~~