Hi Ian,
One has to be careful to use the proper words so as not to muddy the waters with different principles which, although related, are distinct. Barr noted that submersed macrophyes typically have a photoperiod of about 8-9 hours, after which food production activities decline. These limits don't seem to apply to algae so that long photoperiods tend to encourage algal blooms while having marginal benefits to plants. The expression "maximum uptake" is more accurately associated with the rate of uptake and of food production. The uptake rate will depend on nutrient/CO2 availability during the photoperiod.
The need to optimize CO2 at the beginning of the photoperiod has more to do with the food prodution inefficiencies at lights on due to the thousands of individual photosynthetic reactions. In other words, the engine s just getting warmed up inthe early part of the period. Fixing Carbon is a top priority, so it has to be available otherwise the system is more vulnerable to shortfalls. That's the reason for the 2 hour gas initiation prior to lights on. It's because of our inability to provide good distribution and saturation that we need to do this.
By the 6 hour mark the plants have fixed plenty of carbon and the injection has saturated the water as well as the fact that the system is starting to shut down, so there is much less emphasis on the gas availability by then. That's why we can shut the gas off early without ill effects. A lot of our CO2 problems actually are occurring in the early part of the photoperiod.
Cheers,