Yes, CO2 decreases pH as it combines with water to make some acid (carbonic I think, H2CO3 makes sense right?), so lots of photosynthesis will mean less CO2, and an increase in pH. Adding CO2 would be the solution, but may be overkill, as it's a bit of hassle.
To test this theory you should test the pH at the maximum and minimum times of the day. So pH should be high in the afternoon (after lots of sun) say 4pm, and then lower very early in the morning 4am. Best to test on a sunny day obviously. If you see this stark change then you can be sure it's to do with photosynthesis I would say.
You can always check the rocks by taking them out and putting some ordinary white vinegar on them. If they foam then they are calcareous and will be increasing the pH. This might be worth it if you aren't exactly sure what all the rocks are.
Bear in mind that the effective toxicity of ammonia goes up with pH, and also don't forget that pH is log scale. I'm sure you have ammonia under control anyway, but basically this means that ammonia is a lot more toxic at pH8.2 compared to pH7. More than 10 times as toxic at least. I'm sure you are looking after your tank so ammonia isn't an issue anyway
To test this theory you should test the pH at the maximum and minimum times of the day. So pH should be high in the afternoon (after lots of sun) say 4pm, and then lower very early in the morning 4am. Best to test on a sunny day obviously. If you see this stark change then you can be sure it's to do with photosynthesis I would say.
You can always check the rocks by taking them out and putting some ordinary white vinegar on them. If they foam then they are calcareous and will be increasing the pH. This might be worth it if you aren't exactly sure what all the rocks are.
Bear in mind that the effective toxicity of ammonia goes up with pH, and also don't forget that pH is log scale. I'm sure you have ammonia under control anyway, but basically this means that ammonia is a lot more toxic at pH8.2 compared to pH7. More than 10 times as toxic at least. I'm sure you are looking after your tank so ammonia isn't an issue anyway








