Some people seem to think that because the hot water may sit for longer in the pipes it will pick up copper etc.
Personally I'm not too convinced and I've spoken to people that have been using water from the hot tap for years without any problems.
I think it is a bit of an old wives tale coming from the days when people still had lead pipes, header tanks and huge storage tanks in the loft that things would occasionally die in and hot water tanks where hot/tepid water would remain in all day.
Today many if not most houses have hot water on-demand just water heated straight from the cold supply, so no header tanks in the loft and no hot water hanging around at questionable temperatures, .
I still can't bring myself to fill the kettle up from the hot tap so I can see where the nay sayers are coming from.