37 gallon isn't a bad sized tank, so no worries there! You can still do a lot with it.
No worries about air. The airstone should be enough. As long as there is surface disturbance to allow for gas exchange, and the temp isn't too high, there shouldn't be a concern about oxygenation.
The total stocking is about a lot of factors - whether the fish need a lot of floor space, like cories (and plecs, and what type of pleco do you have? Bristlenose don't get massive, but common plecos do...if you upload photos of your plec, I'm sure someone here will be able to ID it!), or height, like angelfish; the type of stocking you already have; your filtration, maintenance routine, whether you have a lot of live plants, size of the fish as adults - lots of factors, so try to ignore rules like "1 inch of fish per gallon", because they were really only meant to be a rough guideline, and isn't terribly accurate.
Are you able to test the hardness of your water at a nearby fish store? You can take a sample of water to a store and ask them to test the GH. Make sure to write the number down and let us know what it is, since that can tell us what types of fish will do best in your water. For example, all of your fish prefer softer water (lower GH) apart from the guppies, which need hard water to thrive.
Once you know your GH, you can select any new additions based on which will thrive best in your current water conditions.
But for now, I wouldn't add a new species of fish to your tank. I would get some more black skirts and some more neons, so that they have proper schooling numbers. Theses type of schooling fish really need to be kept in groups of at least 8 (and the more the better, tank size allowing, since they live in groups of thousands in the wild) to keep them happy, and for you to see their full behaviours properly.
Do you have a filter on the tank? What kind? Any live plants?
So in your shoes I would ask your parents to take you to the fish store, take a sample of the tank water with you (and ideally, a sample of your tap water to test separately so you can compare) and ask them to test the GH, pH, ammonia, nitrite, and nitrate. Making sure to write down all the numbers for yourself, not just let them tell "it's fine". You need the numbers. Then buy four more black skirts and at least 3 more neons.
Welcome to the hobby! I hope you're enjoying your tank and you stick around here to learn more!
@Byron and
@Colin_T any thoughts or corrections?