The filters should say on them what turnover they are. I used to use a little one which said 260l/h on the side of it. While that was probably a bit of an overestimate, for a 26L tank it was just right so it didn't matter.
Yes on more filters - double the filters = double the media = more bacteria to process ammonia.
A mini-cycle is like a normal cycle. Only instead of it occurring when the filter is brand new and just set up, it occurs when the filter is already mature (ie, already has a colony of bacteria to process ammonia within it), usually when some kind of mistake has been made that kills off some (but not all) the bacteria: could be washing one of the sponges under the tap, letting one of the sponges dry out, keeping the filter off for too long, not not adding dechlorinator quick enough etc, or when a large amount of extra stock is added, thereby increasing the bioload substantially meaning there are not enough bacteria to handle the increased amount of ammonia. The bacterial colony approximately doubles in size every 24hours (ish), so theoretically if you double the bioload then it should only take 24 hours for the ammonia colony to catch up, but then you've also got the nitrite colony to catch up too. I believe 1ppm of ammonia = ~2.4ppm of nitrite or something, so you need to allow at least 3-4 days. They can last 2-3weeks depending on your circumstances, and as we don't know all the possible influences there are on bacterial growth within a filter, there's no way you can really know what your circumstances are - only hope they are good ones! While you have a mini cycle you're in a fish-in cycling situation so you should be testing water every 12-24 hours and doing large multiple water changes to keep ammonia and nitrite under 0.25ppm.
Finally, the heater being too big is not a problem, UNLESS is breaks. A broken 50w heater will cook your fish a lot quicker than a 25w heater, thus meaning you have less time to notice there's a problem and rectify it. I guess it's a risk you need to judge yourself. Personally I always try to use a heater appropriate to the size of the tank. I take it you don't have a 25w heater?