Struggling with PH levels in the acidic range of 4 to 4.5

I still wouldn't add anything that has potential to raise GH in this case, that is already pretty high. I wont recommend limestone and crushed corals. because they will also raise your GH.

I would use a commercial KH booster to raise the alkalinity only and slowly until the PH moves a little over 7. Then maintain it trough water changes.
 

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