As someone from the 'opposite side', (and in no way contradicting waterdrop), I DON'T use water from my hottap do to the concerns over the various metals etc that might be in it that I can't test for.
In my loft I have a plastic storage tank that the water goes in when it comes out of the mains, this is used to provide the hot water 'pressure'.
This in turn fills my hot water tank, which is basically a large tank, usually made from copper, and coated with insulation. It has a spiral of heating pipe in the bottom that the hot water from the boiler runs through, and it is this that heats the water.
The way I see it my 'hot water' from my tap has first sat in my loft for a period of time, then sat being heated in a large copper vessle for a period of time, then flowed through copper pipes, joined with solder that probably contains some lead, (as lead free is fairly recent), and then comes to my tap.
The API dechlor I use does (according to them) 'deal with copper', but who knows to what amount, and to be honest I figure with the amount of copper construction in my heating system, I'd rather not take the risk than to come down one morning after a water change to dead fish/shrimps and "Oh... I guess there was to much copper in it after all..."
As waterdrop says, it really depends on YOUR system, and YOUR feelings on the matter. I think if I had a system like waterdrops then I'd probably use the hot tap water, but in my situation there just to much copper involvement and to many unknowns for me to feel comfortable doing it. A few kettles of boiling water, and even on a fairly big water change the water is then only slightly cooler than the tank
