A healthy tank should smell like freshly turned earth. With appropiate water changes, gravel cleaning, and filter maintenance this is all the smell you should have coming from your tanks. If you have spilled tank water on the floor without using a disinfectant to neuteralize the bacteria you will get a foul smell.
I use a mix of 1 part bleach to 20 parts water, along with a good shot of laundry detergent on my fishroom floor. If my 8'x16' fishroom doesn't smell fishy your room shouldn't. If I leave spilled water without mopping it will smell fishy after a couple of days, and totally disappears after mopping with a little bleach.