I was looking up the ingredients of Hikari Shrimp Cuisine as it said it contains copper and I thought it was odd as I had heard copper is toxic to invertebrates. I came across this post from ThePlantedTank and thought it was quite interesting.
"[background=rgb(245, 245, 255)]To be a stickler for terminology, shrimp don't have blood or a closed circulatory system as in vertebrates; instead, a fluid called hemolymph sloshes about within the body cavity. The oxygen-carrying molecule in their hemolymph is hemocyanin, a respiratory protein which binds oxygen using [/background]two copper atoms[background=rgb(245, 245, 255)]. [/background]
[background=rgb(245, 245, 255)]According to [/background]this paper[background=rgb(245, 245, 255)], decapod crustaceans (like shrimp) need around 31.3 to 38.1 μg (1 μg = 1/1,000,000 of a gram) of copper per gram of body mass "to meet the requirements of both copper-associated enzymes and the copper bearing respiratory pigment haemocyanin". [/background]
[background=rgb(245, 245, 255)]The line between need and toxicity [/background]can[background=rgb(245, 245, 255)] be fine ([/background]source[background=rgb(245, 245, 255)]), but copper is an [/background]essential trace metal[background=rgb(245, 245, 255)] required for copper-dependent enzymes in energy production, pigmentation, and so on.[/background]
[background=rgb(245, 245, 255)]We should distinguish this dietary requirement from the effects of the cupric ion (Cu+2). This is copper's major toxic species -- doing much damage to crustacean gills by inhibiting osmoregulation -- and results when [/background]copper sulfate medications[background=rgb(245, 245, 255)] are added to water ([/background]source[background=rgb(245, 245, 255)])."[/background]
"[background=rgb(245, 245, 255)]To be a stickler for terminology, shrimp don't have blood or a closed circulatory system as in vertebrates; instead, a fluid called hemolymph sloshes about within the body cavity. The oxygen-carrying molecule in their hemolymph is hemocyanin, a respiratory protein which binds oxygen using [/background]two copper atoms[background=rgb(245, 245, 255)]. [/background]
[background=rgb(245, 245, 255)]According to [/background]this paper[background=rgb(245, 245, 255)], decapod crustaceans (like shrimp) need around 31.3 to 38.1 μg (1 μg = 1/1,000,000 of a gram) of copper per gram of body mass "to meet the requirements of both copper-associated enzymes and the copper bearing respiratory pigment haemocyanin". [/background]
[background=rgb(245, 245, 255)]The line between need and toxicity [/background]can[background=rgb(245, 245, 255)] be fine ([/background]source[background=rgb(245, 245, 255)]), but copper is an [/background]essential trace metal[background=rgb(245, 245, 255)] required for copper-dependent enzymes in energy production, pigmentation, and so on.[/background]
[background=rgb(245, 245, 255)]We should distinguish this dietary requirement from the effects of the cupric ion (Cu+2). This is copper's major toxic species -- doing much damage to crustacean gills by inhibiting osmoregulation -- and results when [/background]copper sulfate medications[background=rgb(245, 245, 255)] are added to water ([/background]source[background=rgb(245, 245, 255)])."[/background]