With a tank that size, there's very few limitations.
A few things to consider:
Cost wise, you may want to stick to fish that are comfortable in your tap water... because while you can mess with the water parameters, cost will be something to consider with such a large volume, and should a crisis take place, the first step is (almost) always massive water changes... having the same water parameters in your tank and tap makes that far easier to do fast.
Think big... with a tank like that, you will need to have big features in the tank, otherwise they will get lost. That doesn't necessarily mean that you need big fish, but if you are going with smaller fish (which I am a big proponent of) you'll want to go with very large numbers in the shoals (which actually makes for some GREAT DISPLAYS, more impressive to me actually than simply large fish). But, you'll want either, big plants, big rocks, big driftwood, etc... whatever you go with... bigger will look better.
A tank this size allows for multiple fish with territorial tendancies... the key is that you'll need to add features to the tank in the form of plants, rocks, wood, etc. that break up the sight lines for the fish, so that they can each have their separate territories. They may get into a scrap or two, but as long as each has their own 'neutral corner' to retreat to... it will work out.
Let your mind work through all these different scenarios a few times, before you land on one. A tank like this is a major investment (given the scale of the elements you'll need to purchase) and will become a focal point of the house. Take your time, and weigh all the options available to you!