Fish Food

Well, it retains its nutrients better that way :D

Yes, but lots of small fish can't get into it, so the nutrition will be wasted. Whether you boil/mash or not depends on what fish you have; my juvenile platies can't chew a whole piece of raw pea, so I do. It may be more nutritional the other way, but IMO food that doesn't get eaten is rather wasted, nutritionally speaking...
 
In mature peas, the seed shell, also known as the endosperm, is almost completely consumed when harvested. Mature peas are the ones where you open the pod and take out the seeds. The inside part, called the cotyledon, becomes the major source of nutrion for a newly germinated plant. So, the shell of that seed actually has far less nutrients than the inner part. I've never heard of anyone feeding their fish pea pods, so I am pretty sure that mature garden peas is what we are talking about here.

See http://www.esu.edu/~milewski/intro_biol_tw...and_Fruits.html for example
 

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