It was probably the plecos picking on his/her tank mates!
To my knowledge, plecos are only agressive to each other, and it's not like they could bite.
But I bet they could give a nasty suck!

Back on topic, I've had mysterious deaths from time to time. I often notice the fish sulking for a day or so before it goes. I've used Interpet anti internal bacteria almost as a preventative measure from time to time, it may help it may not but it makes me feel a bit better knowing i'm trying.
