As underwrlde surgested, you need to strip and re-clean the tank. Use 1part bleach to 10parts water, and soak all overnight, before scrubbing the lot, and replacing the filter/filter media. I would change to the fluval, due to increased flow rate, and greater amounts of media. Rince all like crazy after the bleach soack, as any trace of that remaining will kill the filter bactiria. use the venturi device (air thingy) on the fluval, to boost DO levels in the tank, and promote the growth of the bactiria. also, crank the temp up to arround 32 centigrade, to aid quicker bactiria growth. The film and smell combined would surgest to me that there may have been a lock of DO (disolved oxygen) in the water, caursing the death of the airobic bactiria you want, and anairobic bactiria forming. These breakdown nitrAte, supporting the drop from 10ppm to 0 as you mentioned earlier, and give off small amounts of oxygen, nitrogen and some other bad smelling chemicals. Surface agitation will remove the smell after a while, and release the nitrogen into the atmosphere. If this film appears again, position the fliter outlet so that the surface is agetated by the outflow of the filter. This may mean tilting the fluval.
HTH
rabbut