Yup. Mollies can be converted to full salt water if you raise the salinity slowly enough.
A 30 minute acclimatisation will be more than enough to take mollies from FW to marine and nmonks often comments that mollies can be taken from fw and placed into sw with no acclimatisation. It would seem, therefore, that slow enough equates to almost instant in this matter.
And to return to the catfish comment about scaleless fish being burned by salt; not only do catfish exist in bracksih and marine waters (the families Ariidae and Plotisidae spring to mind) but so too do many eels (consider the moray eels). Eels do not have scales either yet manage to survive fine in marine waters.
So then, why are so many catfish so intolerant of salt in their water? It has to do with their osmoregualtory system (the system which maintains the internal salt levels through interactions at the gills for the most part). Many catfish and tetras have spent millions of years in the mineral and salt poor waters of South America and as such have an osmoregulatory system designed for keeping pretty much every mineral and salt the body wants inside. When they are placed in waters with significantly higher levels of salts and minerals (such as brackish and marine) then the body starts to take in far more than it wants at the expense of losing water; they become hypersaline.
The reverse occurs with Salt water fish; they take on too much water and lose salts and minerals becoming hyposaline (though studies appear to show that marine fish are more euryhaline than freshwater fish - that is marine fish live at a lower salinity better than freshwater fish live in a higher salinity).
So the above is why some catfish (as well as other fish) do poorly in salted water. It should be noted that there are variations in how well fish cope with levels of salt. To take the genus
Corydoras as an example, some species perform extremely poorly whilst others appear to be able to survive well for some time at a specific gravity of 1.003 and above.
Finally, I am not aware of salt as a medicinal use (such as short term to deal with ich or some such ailment)being a problem.