Any idea what this brown stuff is?

As Wolf says it's diatoms, sometimes known as brown algae though they're not really.
Often caused by too little light, but are also very common anyway in new tanks; something to do with the general instability of the tank. I had them when my tanks were new, and thought it was because the light bulbs were not strong enough, but they have gone away now. They are harmless to the fish anyway.
 

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