Adding chlorinated tap water directly to an aquarium and expecting everything to be alright is asking for trouble. Whilst dechlorinators do neutralise chlorine/ chloramine as soon as they come in contact with the chlorine molecules, it takes time for the dechlorinator to come into contact with all the chlorine. If you add tap water directly to the tank, there will be free chlorine in the tank water for as long as it takes the dechlorinator to neutralise it all. During this time, the fish and beneficial filter bacteria will be exposed to chlorine and suffer some damage.
The best thing to do is get some large plastic containers and fill them with tap water. Put in the required amount of dechlorinator. Add an airstone and let the mixture aerate for at least 5 (preferably 30) minutes. This allows the dechlorinator time to come in contact with all the chlorine and neutralise it. And it allows the water a chance to re-gas. When water is under pressure, the dissolved gasses in it can be forced out. Aerating the water for 30 minutes or more, can let the gasses in the water get back to normal levels. This means the new water won't be lacking oxygen, carbon dioxide or nitrogen. If these gasses are not in the correct balance, the fish can suffer.
For large tanks, you use large plastic containers to make up the water. Then use a water pump and some plastic hose to pump the dechlorinated water into the aquarium. You can make a U shape out of pvc pipe and attach one side of the U to the end of the hose so it hangs over the side of the tank. Turn the pump on and the U will hold the hose in place and direct the new water into the aquarium.
People get away with filling aquariums directly from the tap and adding dechlorinator to the tank for a long time. But one day you will kill the fish. The water companies do work on the pipes and add extra chlorine/ chloramine to make sure nothing is alive in the water, and they don't tell you when they do this. If they do work on the pipes and increase the chlorine/ chloramine levels, and you put that heavily chlorinated water directly into your aquarium, you will lose fish.
All new water should be free of chlorine/ chloramine before it is added to an aquarium containing fish, shrimp, frogs, or any other aquatic life forms.