You can buy 'pure' ammonia as a household cleaner. It's actually a solution of ammonia in water, as 'real' pure ammonia is too powerful to be sold to the general public! It's usually 9.5% ammonia and the rest water.
Some of them have soap and other cleaners added: obviously you can't use those, but the pure ammnoia is fairly easy to get hold of.
Boots do one, if you're in the UK, although you have to order it online to be collected from the shop; 'KleenOff' is a brand that I believe is widely available in the US, and they are plenty of other suppliers too; you can even buy it on Amazon and Ebay.
A fishless cycle, to explain it very simply, invloves adding enough ammonia to the tank to get to around a 4 or 5ppm concentration, then waiting for the ammonia to disappear.
Once it has, you keep adding and testing, until all the ammonia has gone when you test 12 hours after adding it.
Of course, you have to wait and test for nitrite as well, as that is the second part of the nitrogen cycle, which goes;
ammonia > eaten by bacteria > nitrite > eaten by bacteria > nitrate > water change.
I don't personally use it, because I started fishkeeping a long time before fishless cycles using ammonia were known about.
I did do a fishless cycle, but using fish food left to rot in the tank, which also produces ammonia, but that's a very messy and rather smelly way of doing things, though it does work.
Nowadays, I just 'clone' filters for new tanks, but I always recommend fishless cycles to newcomers to the hobby.
If I ever had to get rid of all my tanks and start again for some reason, I would do a fishless cycle with ammonia, no doubt about it at all.
It's a lot less hard work than a fish-in cycle, which can invlove a lot of water changing to keep the ammonia at a low enough level to be safe for the fish and there's always a risk of killing fish if it goes wrong, which just can't happen in a fishless cycle.
Edited for spelling!