humm have we any chemists in the house? having talked to one, my dad, it would seem that most of the rocks stated as unsafe, are infact quite safe. on the whole all the rocks mentiond, do leach, and will raise and lower your ph and add things to your tank. but the fact is that most would be safe in any aquarium, the amounts of undesirable chemicals are quite small. sand stone is sited as unsafe for aquria, in this thread and the posted link. but even the linked post says infact that it can be used!!!!! the theory behind these rocks being unsafe is quite sound, its just that, as with many things, theory and real life practice often seem to contradict each other.
lol Shells are said to be unsafe in tropical aquaria. this is untrue. granted if you pound then in a strong current against rocks and other shells they will release their Calsium. but its not going to happen in your average tropical setup.
This is not to say that ALL rocks are safe!!!!!!! research is always well worth the effort.