They are almost all alcohol or "spirits" based today -- you'd be hard pressed to find a mercury one anymore. The tough part is that it isn't easy to determine the exact kind of spirit that is in there -- it may be ethanol, kerosene, toluene, or isoamyl acetate are the common liquids I could find with a quick search.
I'd do a large water change, just match the temperature and pH and hardness of the water, and you can do as large as a 90% water change without any effects. I wouldn't worry about ethanol or isoamyl acetate in the water, but i wouldn't want kerosene or toluene in there. They will all be very dilute in such a comparatively large volume as the tank, but waster changes cure almost any problem like this.