Just a quick observation about testing for ammonia, nitrite and nitrate. The chemical formula for these things is NH3, NO2 and NO3. there are two ways to measure for these things. the first is the Nitrogen scale and is the one favored by the scientific community. This scale only measure the N part of these things. This is the scale used by the Nutrafin test kits mentioned by Malok in post #4. Using this scale 1 ppm (which = 1 mg/l) of ammonia = 1 ppm of nitrite and 1 ppm of nitrate. This is because science is usually concerned with the nitrogen levels.
However, the API test (and many other we use) measures using the Total Ion scale which measures all of the components involved.
There are two major ways to describe the concentrations of ammonia, nitrite, and nitrate in water. The "nitrogen" weight of these molecules describes the weight of only the nitrogen atoms within them. On the other hand, the "ion" weight of these molecules describes the weight of the entire molecule.
For example, the term nitrate-nitrogen (NO3-N) refers to the weight of only the nitrogen atom within the nitrate molecule; as opposed to nitrate-ion (NO3), which describes the weight of the entire nitrate molecule. Note that a given nitrate-nitrogen value will always be lower than the associated nitrate-ion value. Conversion between the two forms is as simple as applying a constant (see graph below).
Scientific literature often uses the "nitrogen" form rather than the "ion" form to describe the concentration for these molecules. The "nitrogen" form is more appropriate when discussing nitrification/denitrification cycles, as it simplifies various equations and flow-charts. For example, it is easy to see that 100 ppm of nitrite-nitrogen (NO2-N) can go on to form 00 ppm of nitrate-nitrogen (NO3-N). Using the "ion" form here would be more cumbersome; 100 ppm of nitrite (NO2) goes on to form approximately 135 ppm of nitrate (NO3).
Note that a total ammonia value (NH3 + NH4) cannot be trivially converted from "nitrogen" to "ion" form or vice versa. The total ammonia value must first be broken into component NH3 and NH4 values, then those converted individually to NH3-N and NH4-N and added together. The Free Ammonia Calculator can be used to do this. |
NH3 = NH3-N * 1.21589 |
NH4 = NH4-N * 1.28786 |
NO2 = NO2-N * 3.28443 |
NO3 = NO3-N * 4.42664 |
Assumed atomic weights:
H: 1.008, N: 14.007, O: 15.999
This matters for a few reasons. A perfect example is Dr. Hovanec's directions for fishless cycling. In these he talks about not letting ammonia or nitrite from getting above 5 ppm on the nitrogen scale. But if one is using API kits those numbers will be higher. so you have to apply the above formulas. Ammonia should not get above 1.28 that is because the ammonia because most if it will turn to NH4 (ammonium) in water, So the ammonia level not to exceed on an API kit becomes 6.4 ppm and nitrite becomes 16.4 ppm. Whichever scale onre uses exceeding the numbers will normally stall the scale or else develop the wrong strains of bacteria.
Also the solution for dealing with nitrite in a tank with fish is not to change water, it is to add chloride as it, in effect, block the nitrite from entering the fish. If you want to know how to do this read about it in this article on the site
https://www.fishforums.net/threads/rescuing-a-fish-in-cycle-gone-wild-part-il.433778/
Thank you for this detailed reply!
You had me dusting off my old chem minor here, but I do understand the above. Over on the salty side of things, we talk a lot about total ammonia vs. free ammonia too.
Let me first say that I looked for the test kit
@MaloK posted above, and I didn't see good source of that kit here in the US (<read: a store I'd feel comfortable ordering from). So I'm not sure this kit is going to be an option for me. Or, like you said later in your post, I may not want/need to test for all those parameters. But just to make sure I understand, the JBL test kit mentioned above uses only the nitrogen content of each molecule/ion, but the API tests for the whole molecule/ion. Is that right?
I've watch Dr. Tim's extended talk on cycling marine tanks several times; good stuff for sure. I can provide a link to that talk if anyone here is interested. For a fishless cycle, I don't tend to let the ammonia get quite that high, I would fishless cycle my marine tanks at about 2.0 ppm to maybe 3.0 ppm. It can go higher safely, but indeed if too high and you stall the cycle. So I would think any of the kits are going to get me in that range safely.
Outside of the the initial nitrogen cycle, I see no need to test for ammonia or nitrite in a healthy, running system, short of some emergency that makes me suspect that the ammonia is high. So most of what you're saying is going to relate for any ongoing nitrate tests I may do.
I'll add, on the salty forum I frequent it's largely agreed/understood that the presence of nitrites will cause artificially high results for nitrates when tested. I would have to assume the same would happen with freshwater tests too. Do you have any experience or knowledge of that?
To me, none of the hobby level kits we use are laboratory accurate. I prefer to look for trends, such as, ammonia went up and has now come down, rather than hard numbers. But this info is all good stuff, and I very much appreciate conversation like this! I'm already liking TFF better than one of the other freshwater sites I tried.......
I have had as many as 13 planted tanks over the years. For almost 10 years, I ran a high tech pressurized CO2 added tank. Early on I was trying to test a bunch but ultimately stopped. I settled on a dosing regimen that seemed to work fine as I grew any plant I wanted in that tank.
So, my answer would be I almost never test for anything in relation to the plants in a tank. In fact, unless I am running my bio-farm to cycle filters, I do not test almost anything ever. I did monitor my Altum angel tank using a a continuous digital monitor which measured conductivity or TDS, temp in F or C and pH. But that was because I lowered the 1st and 3rd parameters from those of my tap. In the end, my current planted tanks are now all lower light and use a limited number of species.
I fertilize weekly after water changes with Tropica liquid ferts and have done so for over 20 years. I also add Flourish Excel at that time and dosing at the rate of 3 ml/10 gal. of water. Finally, I use Jobe's fertilzer spikes for Lish Ferns & Palms as my substrate fert. These can be cut to needed sizes. But, if you want to use them, never uproot them as they are slow release buried but not in open water. If you let them get into the water becuase you like to replant now and then and so remove some plants to put in the new ones, you may soon earn your aquarium MBA (Mastered by Algae). The box below lasts me for years. I add them at 3 month intervals in March, June, Sept., and Dec. for crypts, swords and planys I have in pots.
View attachment 366512
Buy them on Amazon
But many planted tank folks do test a lot and they have indicated this in their posts in this thread. I am a minimalist who is guided by the kiss theory which means, "Keep It Simple, Stupid." So I do. You will just have to discover what will work best for you and once you do, keep on doing it.
I prefer to use a small size gravel for planted tanks. I also feel that most of the pricey planted tank products are a complete waste of money. This is just my opinion though.
Finally, this chart may help you determine what is causing your plants look poorly:
Thank you again for the above information; very helpful!
I'm already a pretty good algae farmer, I don't need an advanced degree in it lol!
I have gone back and forth on this, but considering I have other projects around the house right now, I think I'm going to save the expense of going with a CO2 injected system here, and opt to try a low-tech system once more. I believe where I'm going wrong on this tank is that I'm using a powerful light, but not giving the plants enough food for the rapid growth. I believe the plants I want to keep can handle high PAR if they are well fed.
With this in mind, I may not be incline to be testing every little parameter, this will likely be just tap water, and only plants that will do well in those conditions. So problem solved; mods please close lol!
Thanks for the tip on the Jobes! I have in the past stuffed Osmocote in gelcaps, or used the Seachem root tabs.
I'm not familiar with the Tropica ferts, but I have used the Seachem Excel. NilocG Thrive was what I was going to try this time. I have used the Seachm Flourish before, but have now learned it's rather dilute and mostly micros; Thrive appears to be more complete, from what I've read.
Do you feel that the Seachem Excel is a good source of carbon on low-tech tanks? Does it really help?
Thank you for the chart, it's very helpful. Very similar to terrestrial plant gardening too
Thanks again for your help and suggestions, I really appreciate it!