This is a response I received when I sent an email to Mars Fish Care or API with the same question. I hope this helps.
Each reagent bottle has a Lot # printed on the bottle. The last four digits are the month and year of manufacture. Example: Lot # 28A0108. This is a pH reagent manufactured in January of 2008.
Wide Range pH, High Range pH, Ammonia, Nitrate, Phosphate, Copper, Calcium and GH all last for three years.
Nitrite and KH will last for four years.
Freshwater pH (low range) and Pond Care Salt Level will last for five years.
I would not use or trust these kits after they have expired.