You're supposed to submerge the green "diffuser" in water and fill it up by pressing on the top of the pressurized can. This releases CO2 into the diffuser. You won't see anything coming out of it btw.
It's supposed to be filled up a few times a day, depends on how much you see dissappear.
When they talk about releasing the CO2 at night, I assume they are talking about getting rid of any CO2 still in the green diffuser. They're just covering their backs but is no way you could gas out a tank with this piece of equipment.
All in all, it doesn't really do much. Liquid carbon is better.