I agree completely with everything essjay has posted here, including the fact that the water is too soft for swordtails.
At this stage, you should not start experimenting with increasing the GH, because this is a very complex subject and there are ramifications to these additives. And on that note, do not use baking soda. This is not a permanent buffer and it can do more harm than good to fish.
The GH as essjay said is the dissolved mineral content of the water. This impacts fish very much, because all freshwater species have evolved over thousands of years to function ion very specific water. Some species, such as all livebearers (guppies, platies, swordtails, Endlers, mollies) must have mineral in the water or they cannot carry out their physiological processes. The fish works harder and harder trying to manage, but it only weakens, making it more susceptible to other issues and it will always die prematurely, guaranteed. Soft water fish have evolved to function without these minerals, to varying degrees, and they will have problems if they are forced into water where they have to deal with minerals. This is just the GH; the pH factors in as well.
The point here is that raising the GH to benefit the swordtails will make life more difficult for the neon tetra and pleco which are soft water species. And before someone brings it up, yes, there is some adaptability with some species, but it is limited and the bottom line is that soft water species will always be healthier in soft water.
So, once we pin down your GH, assuming it is going to be on the soft side, you should forget livebearers and look for other soft water species. This tank is not suited to swordtails anyway so this avoids that problem (a larger tank). We can consider suitable species.