Slate is safe to use for a tank. At one time it was the main thing used as a tank bottom before tanks started being made from all glass with silicone sealant. I still use one of those slate bottomed tanks for my Xiphophorus nezahualcoyotl breeding colony. They do not know the difference and simply thrive in their tank. Note: nezzy swords do not know any better and simply act like LFS swordtails but they carry very long swords as their defining characteristic. Yep, my antique tank also has stainless steel corner bracing instead of relying on that same silicone to seal the corners of the tank.
Some angel fish breeders also use a piece of slate as a place for their fish to lay their eggs.