I sincerly hope you havent done the large waterchange recomended yet, as doing so is asking for a case of toxic shock that will wipe the tank

You are dealing with OTS.
EDIT: explaination;
NM, just re-read, and seen the waterchange has been done. You can only hope that the tank does not crash now
OTS AKA Old Tank Symdrome occurs when the waterchange regiem is not enough to cope with the bio-loading on the tank. Toxins build up (nitrate is the only one of many toxins involved that we can test for, so only use nitrate as a guide here) and minerals are used up by the fish and get depleated. The fish can addapt to this easily, but the poor water quality will kill any new fish, and the pH will eventually crash, killing the current inhabitance...
The tank is overstocked, hence why you have a raging nitrate issue despite 50% fortnightly waterchanges. For most tanks, that would be sufficient, but not one that is stocked at 2.8 inches per gallon, assuming you only have one of each of the first three species all of which should be in a bigger group than one (bar the gourami)
I would surgest moving more than just the barbs across the the new tank once it is cycled. The Bosmani rainbow (and 5 new friends if it is alone, they need a group of 6+) should be transfered, as franckly a 10g isn't big enough for this active fish, along with the gourami. The new stocking will be more managable for you with weekly waterchanges than the current one.
As a rule, nitrate should be no higher than 20ppm above that of the tap water in a well maintained tank. 20ppm will be impossible to maintain for many in the UK, who's water supply comes in at 50ppm, the leagal limit for nitrate
When treating OTS in future, you want to start with small daily (5-10%) waterchanges for a week, then double the origional volume for a following week and then into a revised waterchange plan. Toxic shocks works two ways. If you lower the toxin quickly it will have the same effect as dropping a fish from water with no nitrate strait into the tank. For most spiecies the result will be toxic shock and death soon after

Gently gently should be your advise for OTS in future guys
All the best
Rabbut