rabbut
I don't bite, all that often...
The tank will cycle for the bio-load in it. Its a supply and demand thing. One fish produces a small amount of ammonia and the bacteria then process this for you, so yes, you can cycle with one fish, and in theory the cycle will complete quicker.
The only issue is that you can only add one more fish after the tank has settled on zero ammonia and nitrite for a week, so progress will be slow for the first few weeks, as you can only double your fish numbers in a week in safe and realistic tearms
The slow progress though, will be better for the fish, as they'll go through less ammonia and nitrite poisoning.
Guppies aren't hardy IME. The used to be, but they are now that imbread, that they have lost all stress. Few will make it past a month in a tank before dieing due to parasites. To be able to breed these comercially, importers keep them drugged up on anti-biotics while growing them on, and they just can't cope without them these days. If you want guppies in the future, try to find a local breeder, as they should have some better stock
The pH is low, and you state the hardness is also. Mollies come from hard brackish water, so this may be the issue. I'd carry on with one only for now, and if it survives, get another fish after a week of the ammonia and nitrite remaining zero. Avoid mollies though, as they clearly don't like something in your tank ATM, and I don't think it will be just that it is cycling
HTH
Rabbut
Edited for spelling


Guppies aren't hardy IME. The used to be, but they are now that imbread, that they have lost all stress. Few will make it past a month in a tank before dieing due to parasites. To be able to breed these comercially, importers keep them drugged up on anti-biotics while growing them on, and they just can't cope without them these days. If you want guppies in the future, try to find a local breeder, as they should have some better stock

The pH is low, and you state the hardness is also. Mollies come from hard brackish water, so this may be the issue. I'd carry on with one only for now, and if it survives, get another fish after a week of the ammonia and nitrite remaining zero. Avoid mollies though, as they clearly don't like something in your tank ATM, and I don't think it will be just that it is cycling

HTH
Rabbut
Edited for spelling