Yeh Convict and Firemouth will happen, but you wont see the others crossing.
I'm not a fan of mixing Centrals with South Americans personally, everytime i have doen it, it has never worked out, the behavior is just to different...much like mixing Africans with New Worlds, although CA and SA are more closer related, it still seems to screw up over time.
Of course popel do it for 6 months and say...its fine!... its when you have adult fish that are tryign to establish territory when you get the problem.
Souths are far more tolerant of each other than Centrals, plus Souths like to pair off from groups, wheras most centrals will breed with anything, includign other species.
Central American Cichlids will not breed with South Americans, and if they do, the eggs will not fertilise, alot of people have a misconception on this as they seem to think Blood Parrots are Central/South cross, but if you look deeper, its pretty well known they are 100% central american crosses (Midas x Red Head x Midas x Red Head)
Souths will not cross outside of there genus, meaning yes a Blue Acara MAY cross with a Green Terror, or yes a Heros Efaciatus MAY cross with a Heros Severus, but it is still alot more effort than it would be for say a Midas to Cross with a Red Devil or a Convict to cross with a Honduran Red Point.....plus you wouldnt get a Severum x Green Terror because they are of different genus, however Centrals are not bothered about that and you can get some crazy crosses!
So to narrow it down... a Blue Acara no matter what the sex will not successfully breed with a Firemouth, and its unlikely they will even try as BA's need to be paired and bonded, whereas a Firemouth is Promiscuous.
And future issues is 2 x 8" fish that are arguing over the same territory in different ways, causing communication errors...which can result in unhealthy fish or deaths depending on the species.