Well, there is nothing stopping you trying.
Just be shure that you keep VERY close tabs of KH, GH and pH. Disragard pH and GH for the most part, be be aware of where they are, readig wise. If the KH drops too fast, you will reduce the fishes ability to excreet ammonia through their gills, and this can lead to them poisoning themselves to death, through not being able to remove bodily toxins

If you do try to change water chemistory, the key thing is to do it slowly, once the fish are settled.
For breeding, I cannot remember the exact stats, but they should be something like KH of 1-2, GH about 4-8 and a pH of 6.5. pH is least important, as it is the KH that will affect how viable the fishes eggs are

A high KH makes the egg shells harder for the males sperm to penetrate, hence you get a higher infertilty rate with higher KH. If they are happy in the water they are in, they will breed regardless, it's just egg viabilty that should be affected by KH.
Some breeders report quicker growth rates with harder water, so I'd be tempted to leave things be untill you get a pair and a round of eggs, then drop the KH and GH towards the target over a week or two. Discus usualy eat the first few batches of eggs I'm told (not actually got as far as breeding them myself yet), so delaying the water condition changes untill later will have no affect on the outcomes of the first batches of eggs anyway.

If left with the parents the first few times, they are doomed to failure from the outset. Don't be shocked if it takes 10+ tries for them to get their young to the free swimming stage

They need parctice to get it right
If you are moving the KH and GH in the tank, add the replacement water SLOWLY to avoid any shocks. Any new water should be mixed in a seporate container, left to mix for an hour ot two, and then tested for KH, GH and pH. Any major difference to the targets, or the tank stats, should be rectifyed at this point, rather than after the water has hit the tank

For low KH, add bicrab of soda. I tend not to worry about GH, unless there is a significant difference, likewise pH. You have to be carful about moving things too fast, and with a KH of 2 in the tank, you will need regular waterchanges and a light bio-load or the pH will crash supprisingly quickly. pH crash is always a risk when you soften water, so keep tabs on KH and pH in your tanks if you do lower the KH. If either slip, it's waterchange time

If you are having to do lots f waterchanges for stability, you need either less fish or more KH in the tank. That desicion needs to be made by you alone, based on where your stats are, and how many fish are in what sized tank.
Usualy for discus breeding, you place the pair into a seporate, dedicated, tank to breed in, of arround 30g, though a 20g tall is OK. This would allow you to move a pair once formed and set-up the water for breeding, seporately to the other fish

It would be a method that I recomend
All the best and HTH
Rabbut