Things you need to know, how old is it? How thick is it? Anything special about it.
Some glass is tempered (modern greenhouses will all be) and you won't succeed in cutting or drilling it. Older greenhouse panels were lethal if you fell through the window as they weren't tempered glass, but a lot of them were made from very thin material which won't be all that much good for a tank.
I've used old greenhouse panel for cover glasses, but never for the actual tank (I've never needed to, float glass isn't all that expensive and I've always managed to pick up 2nd handers for very little). Remember to clean it very well first, greenhouse fertilisers and pesticides can linger.