Sounds like an excellent plan; although a 50-100 litre aquarium may be better suited to a single species than a number.
Costa Rica you have a choice of the following: - Alfaro cultratus, Brachyraphis cascajalensis, Brachyraphis rhabdophora, Brachyraphis parismina, Brachyraphis holdridgei, Brachyraphis terrabensis, Poecilia sphenops, Xenophallus umbratilis, Phallichthys amates, Phallichthys tico, Phallichthys quadripunctatus, Poecilia gilli, Priapichthys annectens or Xiphophorus maculatus.
Of the list above, the Brachy's are only really suitable to a species tank, although the smaller ones such as holdridgei would be suitable, Xenophallus umbratilis would do great if you can find some, but the most likely candidate would be the Phallichthys tico or quadripunctatus. Both are relatively easy to get hold of. Alfaro cultratus would also do well.
Panama you have a choice of the following: - Alfaro cultratus, Brachyraphis cascajalensis, Brachyraphis episcopi, Brachyraphis rhabdophora, Brachyraphis terrabensis, Carlhubbsia kidderi, Carlhubbsia stuarti, Neoheterandria tridentiger, Neoheterandria cana, Poecilia sphenops, Phallichthys amates, Poecilia gilli, Poecilia mexicana, Priapichthys panamensis.
Of the list above, the same comments apply although the Carlhubbsia and the Neoheterandria species would also be suitable.
There are other species but I have left out those which are impossible to get hold of; I have seen most of the fish above in the last 2-3 years; if you need help as to where to get hold of these species then please drop me a line or you could join the British Livebearer Association which would be your best bet.
www.britishlivebearerassociation.co.uk
or the American Livebearer Association
www.livebearers.org