My tank is the fluval roma 200 so space should be OK for a mated pair
The dimensions are as important or even more important than volume because of factors like fish activity (faster swimming fish need more tank length than sedate fish) and territory, which is especially crucial with angelfish as the male will establish his territory. From what I could find online, the Fluval Roma 200 is 55 x 100 x 40cm. This will work for a pair of angelfish, so now I can provide some guidance on this aspect.
Angelfish must select their mates; if they do, they will bond. This can last their lives, or sometimes not, but it is the only way to hopefully have success long-term. Any male put in with any female might bond (a real stroke of luck, but rarely the case) but more often not. Such a "pair" might even spawn a couple times, but then the lack of a bond causes the male to kill the female and it is game over.
The only way to acquire a bonded pair is to observe a group of angelfish in a tank and spot a likely pair. This is not always easy, especially in store tanks where the fish are obviously severely stressed all the time. You could acquire a group of at least five and watch for a pair to form in your own tank, then when it does remove the others. Problem here is, what to do with the other three or more unwanted angelfish. As the fish grow, the space of this tank will be no where near adequate.
Assuming you do end up with a bonded pair, tankmates are possible but must be confined to peaceful and equally sedate fish. Corydoras are usually good as substrate fish, and they don't bother the angels and the angels don't usually bother them. Cories however are very good at eating the egg cluster or the shoal of fry at night when the parents are unable to defend them. But if you do not want to raise fry, this won't matter. However, thee eggs/fry might also survive, eventually, at which time you will have to deal with feeding the fry, and re-homing them.
There are some upper-level fish that can make good tankmates, among the quiet peaceful tetras. Active fish like barbs, danios and active tetras are no good; and any species remotely prone to fin-nip will not work.