Test before you do a water change. I would also test your tap water. Take a sample in a clean container and let it sit for a day or so, shake it once in a while, then test it. Test again after you do a change. This way you will get a better feel for how water changes effect the parameters in your tank. I used up an entire master test kit pretty quickly when I started out. I encourage you to do the same. As time goes on you will use tests very infrequently so the money is well spend gaining experience. I can't remember the last time I tested my tanks, I've gotten to know them so well that I no longer need to test unless I suspect a problem.