Please do not get sedate fish (all cichlids, gourami, etc) if you intend small fish that "may" nip fins. This is like waving a red flag in front of a bull. There are many small peaceful shoaling fish that can be housed with sedate fish, but not these.
Larger groups of a shoaling species may help to contain mild aggressive behaviours within the group. Not always, but sometimes. But placing such a species in close confines with another fish that will bee seen as a welcome sign never works. And any home aquarium is "close confines" to the fish. The pheromones and allomones released by fish that are read by other fish will be present even if physical interaction is not.
Deliberately "risking" is something many of us on this forum do not condone. There is no point in trying something that is contrary to the natural behaviour of the fish species. When fish do not behave according to the norm for that species, it is most often because something has unsettled them, and fish can only react in one of two ways--increased aggression which is proven scientifically to be the usual reaction, or complete withdrawal which means weakened fish and early demise. This is not fair to the fish, just to obtain something we may like. The fish should always come first if we want them healthy and "happy." None of us is going to be able to change nature.
To your question about suitable fish with angelfish or gourami. [But first, the acara will tend to eat anything small enough to fit into its mouth, so if you intend other fish in a community-like tank, this is not the cichlid to select.] Five angelfish need a 4-foot tank minimum; if you honestly intend getting rid of some if a pair forms, this obviously won't be so much of an issue as the pair will likely develop early. I am not a fan of buying a fish intending to get rid of it later. This is stressful to the poor fish. But with angelfish in a 4-foot or larger tank, shoaling species like Rosy Tetra, Bleeding Heart Tetra, Red Phantom Tetra generally work; groups of 10-12 of whichever. These are disk-shaped and better than longitudinal tetras like neons which are much more likely to get eaten; mine certainly were [long before I knew better]. The species mentioned are not fin nippers, though again one can never guarantee this, but there are some within this general clade that are, like the Red Minor or Serpae, and the Widows.