I think the ram at the beginning is male and the ram at 45s is female. They are quite young and I wouldn't expect breeding behaviour for at least 6 months.
The male will have a brighter more brilliant colouration. The ventral fins on the male are usually longer than the females and have a darker blue edging. Caudal fin extensions will develop further too and generally more intense red colouration. The females breeding tube will protrude further and consequently be more visible than the males.
The male will start by swimming around the female closely with all fins erect. The male may also flare its gills quite a lot (a different flaring from aggression though). Lip locking may be witnessed at this time. The male will then continue with his fin displays and begin chasing other fish away as well as pushing the substrate around. He will generally swim closely behind the female. The female, if receptive, will begin responding back to the male with flicking motions. When both fish help each other to dig pits in the substrate spawning should be imminent.
At least, that's what I've observed with mine.
edit: forgot to say, your rams look like they have sunken stomachs. Make sure they get enough food as silver dollars are greedy feeders and may eat the majority of food before the rams get any.