I put my rocks in a bucket and poured on boiling water to sterilise and clean them.
The only advice I can offer is do not boil the rocks themselves. You never boil rocks found in water as they often have water pockets trapped in them. When the water in the rock heats up it can cause the rock to shatter sending rock fragments everywhere.
I don't know what rocks your talking about other than pumice, but the only ones that you can get through in a river are normally your common river rocks that are smooth and thick. Porous rocks or rocks that foster precious gems like geodes or those in the north western United States are the ones that will more likely retain air pockets. But if it's a river rock, it won't crack unless you super cool it and then super heat it all very quickly.