I hate to get too off topic, but DB is only giving half the story:
Everyone knows that water boils at 100 deg C right? Well, sort of. Under careful conditions, you can get liquid water to get above 100 -- and put it in a so called meta-stable state. This meta-stable state can be dangerous, as, like DB said, a perturbation or disturbance can cause all the liquid water to become vapor instantaneously -- it is over 100 after all!
Imagine a boulder perfectly balanced on the tip of a mountain. If completely undisturbed, the boulder will not go anywhere. But, if you push it slightly to one side, it will obviously fall over. On the tip, the boulder could be considered to be in a meta-stable state; stable if undisturbed, but one little perturbation and the system changes rapidly.
Water will only get to this meta-stable state is there is no nucleation point for boiling to occur. Next time you boil water for noodles, look at the metal pan, and at the begining, you should notice a stream of bubbles coming up from one point in your pan. This point is a small imperfection, possibly on the atomic scale, where the transiiton from liquid to vapor can take place. Now, obviously you can't put the metal pan in the microwave, so you use something like a pyrex measuring cup made of glass. The glass can be made very smoothly, specifically, without the imperfections that allow nucleation. So, you can possibly heat your water above 100. Dateline (TV news program in the U.S.) had a report a few summers back of people who burnt themselves quite severely by heating water in the microwave too hot. In this case, it was the jarring of the cup when it hit the counter that caused the metastable water to flash.
RO water has a slightly better chance to become metastable, as tap water may contain solids or particulate matter in it that can act as a nucleation site. But, filtered tap water can be just as dangerous as RO water. The act of adding the minerals in DB's case is a perturbation of the system that will cause it to flash. Adding anything or disturbing metastable tap water is just the same as RO water.
So, next time you heat water up in the microwave in a glass container, consider putting a plastic spoon in there just to be on the safe side.