savior!! recuse one fish and now uve been hooked, sounds like you have MTS already (multiple tank syndrome) lol
all the principles are the same for the fish! you need good water quality, and time to spend looking and caring for your fish!!
depending on the size of the hex tank follow the one inch per one gallon of water rule for now until you get more experienced ie if you get a 10gallon hex tank you can have 10" worth of fish in there! please remember fish grow

so dont go out there and get 10 1" fish that will grow into 4" fish! youll come a cropper
the main difference between your gold fish you have now and tropical is obvioulsy the temperature so one bit of kit youll deffo need is a heater, most hex tanks come in complete setup form so you should get the bits you require when you purchase it from the shop as a guide you should recieve
1 tank
1 heater
1 filter (internal)
1 light (should be built into the tank lid)
1 water start up(purifing) kit
1 thermometer
1 water test kit
make sure you get all this and youll be off to a good start
also you can look at decoration, you may want to consider your options here as there are many, remember you dont have to buy this then and there you can always go back later!
get reading all the "my first tropical tank" "cycling my tank" threads and sticky threads in the forum they will point you in the right direction and get your tank off to a good start!
Remeber patience is key!!! the more patient you are the better long term results you will have!!
Good luck and most of all enjoy it!!
There are many people here to help so dont be afraid to ask questions even if you think its silly, weve all probably asked it in the past!
Andy