The tank size depends on the number of scats and monos. As you probably already know, these are schooling fish and require groups of at least four (some say at least 3, but really 4 is more realisitic). 4 monos, require at least 75 US gallons, and 4 scats require at least 75 US gallons, so at bare minimum youre looking towards at least 150 gallons.
Filtration must be very good as these fish are quite hearty eaters, espically the scats. Its amazing how much food they will eat! Since it would be impossible to plant this tank, I highly reccomended a wet/dry. And since algae grows like weeds in brackish tanks, some mangroves in the sump would be helpful.
I doubt there would be any problem housing these two species together, the big problem that many people dont understand with brackish is their salt tolerance. Just because as fish is labeled as "brackish" doesnt mean that any SG will be fine. For instance, bumble bee gobies, knight gobies, archer fish, scats and glass fish are considered brackish fishes. Just because they are all brackish doesnt mean they can live together. Bumble bee gobies, knights, and glass fish like their SG's 1.005 and under (lightly brackish), which is hardly "brackish" as this is a very small amount of salt. Scats, archers, and monos like their SG's at least 1.010, which is a much larger amount of salt. The jump between 1.005-1.010 may not seem like a lot but it is. The .005 difference means life or death for these fish. Every brackish species tolerance to salt is different, some like a lot, some tolerate little. The most important factor when considering brackish fish is their salt requirements. So read up before buying!
Archers seem to be ideal tank mates for scats and monos, but may be outcompeted for food. Finding suitable tankmates may be hard because like I said, every brackish fish's tolerance to salt is much different. The only other fish that I can think of off the top of my head requiring the same salt needs as scats and monos are green spotted puffers, but they may not be a good option with their aggression and other not so ideal tankmate traits. There are some marine fish that will tolerate the lower salt levels also.