Neons are notoriously fragile, I wouldn't recommend them as a first fish. And as catxx says they are shoalers, so they need to be in a nice big group in a nice big tank to be happy.
Endlers are similar to guppies but tend to be smaller, the females are fairly dull looking but the males are very pretty and stay small. If you use the search function you can probably find some pics.
Bettas aren't particularly difficult to care for. They are very pretty, intelligent and happier in a smaller tank than most fish their size.
Before you put anything in the tank, you need to get it cycled. There's lots of info in the pinned threads about that.
Good luck