The main benefits of using Rooibos are the fact that is stains great and if done as a brewed tea there is no mess in the tanks or filter at all. It will neither soften water nor lower the pH. But it is caffine free. It also has some medicinal properties which are beneficial for fish. Therenis research on Rooibos and fish. Here are a few links from Google Scholar.
Park, S.H., Do, Y.S., Kim, Y.S., Kim, N.Y., Lee, J.H., Kim, J.H. and Yoon, M.H., 2017. Determination of Phenolic Contents in Rooibos (Asphalthus linearis) Tea Depending on the Steeping Temperature and Time. Journal of Food Hygiene and Safety, 32(5), pp.389-395.
Abstract
A simultaneous determination of 5 phenolic acids (gallic acid, chlorogenic acid, caffeic acid, pcoumaric acid, trans ferulic acid) and 9 flavonoids (procyanidin b1, aspalathin, rutin, vitexin, hyperoside, isoquercitrin, luteolin, quercetin, chrysoeriol) in rooibos tea has been carried out by ultra-high performance liquid chromatography coupled to tandem mass spectrometry (UPLC-MS/MS). A validated analysis method in this study was applied to rooibos aqueous infusions. Rooibos tea is an antioxidant-rich tea which has anti-cancer, anti-aging, anti-inflammatory, anti-diabetic effect. Extraction yield of phenolics depends on steeping time and temperature of water. Tea infusions were prepared by placing 1 g of tea leaves or 1 tea bag in 100 mL of boiled water, and then at 3, 6 and 30 minutes intervals the infused teas were taken to carry out the analysis of phenolic contents. Another tea infusion was conducted with cold water (25-30°C) for 30 minuntes. As a result, the total amount of phenolics was highest in rooibos tea steeped with hot water for 30 minutes, followed by 6 minutes, 3 minutes and cold water 30 minutes and the result has statistical significance.
The whole paper only seems to be available in Korean