They all look female at first. You'll be able to tell them apart at 3-6months of age. Keep in mind that the fast maturing ones can be sexually mature at 4 months, and the slower maturing ones will take about 6 months. I have read that the slower maturing ones start out smaller and growing slower than the fast maturing ones, but that by 1yr old the slow maturing males will often be larger than the fast maturing males. I dunno if this is the same for the females.
I have also heard of Livebearers changing sex. I don't know for sure if this happens naturally, but do know that this can be done diliberately artificially by adding hormones to the water. I have also purchased platies that I beleived to be sexually mature females only a couple months later to find out they were males. I don't know if this was an example of natural sex change or just late male maturing.